Product ID:1X1ML, 47385-U, EPA 8240B/8260A (SUPDAT)
MSDS Date:07/20/1998
FSC:6630
NIIN:00N089991
Status Code:A
MSDS Number: CHXJP

SUPELCO INC

SUPELCO PARK
BELLEFONTE, PA 16823-0048
US

Emergency Phone: 814-359-3441

Info Phone: 814-359-3441

Cage: 54968

SIGMA-ALDRICH INC.

14508 ST. LOUIS, MO 63103 US

Telephone: 314-771-5765/414-273-3850X5996

Cage: 54968

200 MG/KG

CAS: 75-35-4

RTECS: KV9275000

Fraction By Weight: 0.2%

OSHA PEL 1 PPM

ACGIH TLV: 5 PPM/20 STEL; 9495

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

1,2-DICHLOROPROPANE (SARA 313) (CERCLA). LD50 (ORAL, RAT)

CAS: 78-87-5

RTECS: TX9625000

Fraction By Weight: 0.2%

OSHA PEL 75 PPM

ACGIH TLV: 75 PPM/110STEL; 9495

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

3500 MG/KG

CAS: 100-41-4

RTECS: DA0700000

Fraction By Weight: 0.2%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM/125STEL;9495

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

500

CAS: 75-01-4

RTECS: KU9625000

Fraction By Weight: 0.2%

OSHA PEL SEE 1910.1017

ACGIH TLV: 5 PPM, A1; 9495

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

5628 MG/KG

CAS: 67-56-1

RTECS: PC1400000

Fraction By Weight: 99-100%

OSHA PEL S, 200 PPM

ACGIH TLV: S,200PPM/250STEL; 95

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

800

CAS: 67-66-3

RTECS: FS9100000

Fraction By Weight: 0.2%

OSHA PEL C 50 PPM

ACGIH TLV: 10 PPM; A2; 9495

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

5000 MG/KG

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 0.2%

OSHA PEL 200 PPM; Z-2

ACGIH TLV: S, 50 PPM; 9495

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

LD50 LC50 Mixture:SEE INGREDENTS.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:OVEREXP EFTS: HARMFUL IF INHALED. MAY
BE FATAL IF INGESTED. LOW BLOOD PRESSURE (HYPOTENSION). DERMATITIS,
BREATHING DIFFICULTY, HEADACHE, NAUSEA, DIZZ, GI DISTURBANCES,
DEPRESSES CNS, NARCOSIS, LIVER DMG, KIDNEY DMG, RESPIRATORY
FAILURE, BLINDNESS, MAY CAUSE CORNEAL INJURY. CONTAINS MATLS (S)
KNOWN (EFTS OF OVEREXP)
Explanation of Carcinogenicity:VINYL CHLORIDE: IARC MONO, SUPP. VOL 7,
PG 373, 1987: GRP 1. NTP 7TH ANNUAL RPT ON CARCINS, 1994: KNOWN TO
BE (SUPDAT)
Effects of Overexposure:HLTH HAZ: TO THE STATE OF CA TO CAUSE CANCER
AND REPRODUCTIVE TOXICITY. REPORTED ANIMAL & HUMAN CARCINOGEN.
TOLUENE APPEARS ON THE NAVY LISTING OF OCCUPATIONAL CHEMICAL
REPRODUCTIVE HAZARDS. SEEK CONS ULTATION FROM APPROPRIATE HEALTH
PROFESSIONALS CONCERNING LATEST HAZARD LIST INFO & SAFE HANDLING &
EXPOS INFO .
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYES: FLUSH W/H*2O FOR AT LEAST 15 MIN. CNTCT A MD. SKIN:
FLUSH W/LRG VOLUMES OF H*2O. WASH CLTHG & SHOES BEFORE REUSING.
INHAL: IMMED MOVE TO FRESH AIR. GIVE OXYGEN IF BRTHG IS LABORED. IF
BRTHG STOP S, GIVE ARTF RESP, CNTCT A MD. INGEST: NEVER GIVE
ANYTHING BY MOUTH TO AN UNCON PERSON. NEVER TRY TO MAKE AN UNCON
PERSON VOMIT. GIVE 2 TABLESPOONS OF BAKING SODA IN A GLASS OF H*2O.
PRESS (SUPDAT)

Flash Point:50.0F,10.0C
Lower Limits:6.0%
Upper Limits:36.5%
Extinguishing Media:CO*2, DRY CHEMICAL, ALCOHOL FOAM.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:FOLLOWING TOX VAPS ARE FORMED WHEN THIS
MATL IS HEATED TO DECOMP. CARBON MONOXIDE, CARBON DIOXIDE,
FORMALDEHYDE, HYDROGEN CHLORIDE, HYDROGEN FLUORIDE, (SUPDAT)

Spill Release Procedures:TAKE UP WITH ABSORBENT MATERIAL. VENTILATE
AREA. ELIMINATE ALL IGNITION SOURCES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.

Respiratory Protection:WEAR NIOSH APPROVED FACE MASK WITH ORGANIC VAPOR
CANISTER.
Ventilation:USE ONLY IN WELL VENTILATED AREA.
Protective Gloves:RUBBER GLOVES.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
MFR'S TRADE NAME PART #: CALIBRATION CHECK COMPOUNDS. EXPLO HAZ:
CHLORIDES. FIRST AID PROC: FINGERS TO BACK OF TONGUE TO INDUCE
VOMITING. IMMEDIATELY CONTACT A PHYSICIAN. EXPLAN OF CARCIN:
CARCINOGENI C. CHLOROFORM: IARC MONO, SUPP. VOL 7, PG 152, 1987.
GRP 2B. NTP 7TH ANNUAL RPT ON CARCIN, 1994: ANTIC TO BE CARCINOGEN.

Boiling Pt:B.P. Text:149F,65C
Melt/Freeze Pt:M.P/F.P Text:-144F,-98C
Vapor Pres:100
Vapor Density:1.10
Spec Gravity:0.79 (H*2O =1)
Evaporation Rate & Reference:>1 (ETHER =1)
Solubility in Water:100%
Appearance and Odor:CLEAR COLORLESS LIQUID.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
STRONG ACIDS, OXIDIZING AGENTS, CHROMIC ANHYDRIDE, LEAD PERCHLORATE,
PERCHLORIC ACIDS, ALUMINUM & MAGNESIUM METALS.
Stability Condition to Avoid:N/A.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE,
FORMALDEHYDE, HYDROGEN CHLORIDE, HYDROGEN FLUORIDE, CHLORIDES.

Waste Disposal Methods:COMPLY WITH ALL APPLICABLE FEDERAL, STATE, OR
LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.